Refractory Bricks

Magnesia Carbon Brick

Magnesia carbon brick (MgO-C brick) is the premier unburned carbon composite refractory for modern steelmaking vessels, specifically engineered for BOF furnace walls, EAF t spots, and steel ladle slag lines.

By combining high-purity fused magnesia (MgO ≥97%) with premium flake graphite (Carbon 10–18%), Highland Refractory provides a lining solution that offers exceptional slag repellency and thermal shock stability at temperatures up to 1800°C.

Our MgO-C series features advanced antioxidant systems (Al, Mg, or B4C) to prevent graphite oxidation, extending campaign life by up to 25% compared to standard basic bricks.

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  • magnesia carbon bricks

    Alumina Magnesia Carbon Bricks (AMC Bricks)

    Alumina Magnesia Carbon Bricks (AMC Bricks) are high-performance carbon-bonded refractory bricks engineered for the most demanding positions in steelmaking equipment—ladle slag lines, converter walls, and secondary refining furnaces. Manufactured from high-purity fused alumina, fused magnesia, and flake graphite, AMC bricks combine the slag resistance of magnesia, the thermal shock stability of carbon, and the high-temperature strength of alumina through in-situ spinel (MgAl₂O₄) formation during firing. Highland Refractory supplies Alumina Magnesia Carbon Bricks with Al₂O₃ 70–80% and MgO 8–15% to steel mills in 60+ countries.

  • Carbon Bricks for Small & Medium Blast Furnace Hearths

    Introduction to Magnesia Carbon Bricks

    Magnesia carbon brick is a non-burning carbon composite refractory with high melting point basic oxide magnesium oxide (melting point 2800℃) and high melting point carbon material which is difficult to be penetrated by slag as raw materials, adding various non-oxide additives and combining with carbon binder. As a kind of composite refractory material, magnesia carbon brick effectively utilizes the strong slag resistance of magnesia and the high thermal conductivity and low expansion of carbon to compensate for the poor spalling resistance of magnesia.

  • magnesia carbon bricks

    Alumina Magnesia Carbon Bricks (AMC Bricks)

    Alumina Magnesia Carbon Bricks (AMC Bricks) are high-performance carbon-bonded refractory bricks engineered for the most demanding positions in steelmaking equipment—ladle slag lines, converter walls, and secondary refining furnaces. Manufactured from high-purity fused alumina, fused magnesia, and flake graphite, AMC bricks combine the slag resistance of magnesia, the thermal shock stability of carbon, and the high-temperature strength of alumina through in-situ spinel (MgAl₂O₄) formation during firing. Highland Refractory supplies Alumina Magnesia Carbon Bricks with Al₂O₃ 70–80% and MgO 8–15% to steel mills in 60+ countries.

  • Carbon Bricks for Small & Medium Blast Furnace Hearths

    Introduction to Magnesia Carbon Bricks

    Magnesia carbon brick is a non-burning carbon composite refractory with high melting point basic oxide magnesium oxide (melting point 2800℃) and high melting point carbon material which is difficult to be penetrated by slag as raw materials, adding various non-oxide additives and combining with carbon binder. As a kind of composite refractory material, magnesia carbon brick effectively utilizes the strong slag resistance of magnesia and the high thermal conductivity and low expansion of carbon to compensate for the poor spalling resistance of magnesia.

Table of Contents (Technical Navigation)

1. Defining Magnesia Carbon Brick: The Steelmaking Standard
2. Grade Selection Matrix: MT-Series Technical Parameters
3. Anti-Oxidation Chemistry: The Role of Al, Mg, and B4C Additives
4. Applications: EAF, BOF, and Ladle Slag Line Optimization
5. Failure Analysis: Why MgO-C Bricks Hydrate and How to Prevent It
6. MgO-C Bricks Selection FAQ

1. Defining Magnesia Carbon Brick: More Than a Simple Composite

The metallurgical performance of a magnesia carbon brick is governed by the synergy between the high melting point of periclase (MgO, ~2800°C) and the non-wetting properties of graphite. Unlike pure magnesia bricks, which suffer from slag penetration and spalling, the graphite phase in MgO-C bricks creates a physical barrier that prevents aggressive basic slags from wicking into the brick matrix.

Highland Refractory utilizes a high-pressure (2000-ton) molding process and specialized phenolic resin binders to achieve apparent porosities ≤4.0%. This structural density is critical for steel plants looking to reduce the "cost-per-ton" of steel by minimizing refractory-sourced inclusions and reducing relining frequency.

Magnesia Carbon Brick

2. Grade Selection Matrix: MT-Series Technical Parameters

Sourcing the correct magnesia carbon brick requires matching the carbon content and magnesia purity to the specific wear zone of the furnace. Below are the standard specifications for our global export series.

Property Grade MT-10 Grade MT-14 (Slag Line) Grade MT-18 (Premium)
MgO Content (%) ≥ 82% ≥ 80% ≥ 76%
Fixed Carbon (%) 10 ± 1% 14 ± 1% 18 ± 1%
Bulk Density (g/cm³) ≥ 2.85 ≥ 2.88 ≥ 2.90
CCS after drying (MPa) ≥ 35 ≥ 30 ≥ 25
Antioxidant System Al / Mg Al-Mg-Si B4C + Al-Mg

3. Anti-Oxidation Chemistry: The Highland Self-Healing System

The fatal weakness of any mag carbon brick is the oxidation of its graphite phase. When graphite burns away, the brick becomes porous and structurally fragile. To combat this, Highland incorporates a multi-tier antioxidant strategy:

  • Metallic Additives (Al/Mg): These react with carbon and nitrogen at operating temperatures to form high-strength carbides and nitrides, effectively "plugging" the pores against oxygen ingress.
  • Carbide Reinforcement (B4C): For ultra-high temperature zones (>1650°C), Boron Carbide acts as a high-efficiency scavenger, forming a liquid glass phase that self-heals micro-cracks in the brick surface.
  • Resin Stabilization: We utilize high-coking phenolic resins that create a carbon-bonded skeletal network, maintaining modulus of rupture (MOR) even during rapid thermal cycling.

Magnesia Carbon Brick

4. Applications: EAF, BOF, and Ladle Slag Line Optimization

Modern steelmaking vessels are "Zonal Lined" to optimize both performance and cost. A single furnace may utilize three different grades of magnesia carbon brick:

  • BOF Lining: High-purity sintered MgO with 10% Carbon (Grade MT-10) is typically specified for the furnace walls and bottom to resist molten metal scouring.
  • Ladle Slag Line: The most aggressive wear zone. Requires Fused Magnesia with 14-16% Carbon (Grade MT-14) to resist the fluctuating chemical attack of basic slags.
  • EAF Hot Spots: Requires premium MT-18 grades with Boron Carbide additives to handle the extreme radiant heat and high-velocity gas turbulence near the electrodes.

5. Failure Analysis: Why MgO-C Bricks Hydrate and How to Prevent It

A critical sourcing concern for foreign buyers is hydration. Magnesia (MgO) reacts with moisture in the air to form Mg(OH)2, which causes the brick to expand and crack during storage. Highland Refractory solves this through:

• Vacuum Sealing: Every pallet is vacuum-wrapped in multi-layer moisture-proof plastic.

• Resin Encapsulation: Our manufacturing process includes a specialized resin coating on the fused magnesia grains to block moisture contact.

• Anti-Hydration Testing: Every batch is tested in a high-humidity chamber to ensure a shelf-life of ≥6 months in humid environments like Southeast Asia or Middle East ports.

Magnesia Carbon Brick

MgO-C Bricks Selection FAQ

How long is the typical service life of MT-14 bricks in a steel ladle?
In standard ladle operations, Highland MT-14 bricks typically achieve 120–160 heats at the slag line, depending on slag basicity and stirring practices.
What is the difference between fused magnesia and sintered magnesia in MgO-C bricks?
Fused magnesia has larger periclase crystals and lower porosity, providing superior slag resistance. Sintered magnesia is more cost-effective and is used for non-contact backup or safety linings.
Can you provide custom wedge-shapes for converter bottoms?
Yes. We use CNC-grinding and precision 2000-ton hydraulic presses to produce custom wedge, arch, and key-shaped bricks with ±0.5mm dimensional tolerance.
Do your magnesia carbon bricks require pre-heating (baking) before use?
Since MgO-C bricks are unburned (resin-bonded), a controlled baking cycle is mandatory to carbonize the binder and activate the antioxidant systems before full thermal loading.
What are the lead times for global exports?
Standard MT-series grades ship within 30–35 working days. Custom geometries require 45 working days for mold fabrication and production.

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Related Products

magnesia carbon brick

Magnesia Carbon Brick

The main raw materials of magnesia carbon bricks include fused magnesia or sintered magnesia, flake graphite, organic bonds and antioxidants.

Magnesia Carbon Brick

High melting point basic oxide magnesium oxide (melting point 2800℃)

Alumina Magnesia Carbon Brick

Magnesia Carbon Bricks

In the harsh environments of steelmaking and metallurgical processes—where extreme temperatures (up to 1800℃), aggressive slag erosion, and frequent thermal shocks dominate—refractory materials are the unsung heroes that ensure operational stability, reduce downtime, and control costs. Among these, magnesia carbon bricks (MgO-C bricks) stand out as the gold standard for critical applications like basic oxygen furnaces (BOF), electric arc furnaces (EAF), and ladle slag lines. Engineered by combining high-purity magnesia (MgO) with graphite and advanced carbon binders, these unburned carbon composite refractories leverage the complementary strengths of their components to outperform traditional refractories in durability, corrosion resistance, and thermal stability. This comprehensive guide unpacks everything industrial buyers, steel mill engineers, and metallurgy professionals need to know about magnesia carbon bricks—from their composition and properties to applications, technical specifications, and why they’re the preferred choice for high-demand metallurgical environments.

Carbon Bricks for Small & Medium Blast Furnace Hearths

Introduction to Magnesia Carbon Bricks

Magnesia carbon brick is a non-burning carbon composite refractory with high melting point basic oxide magnesium oxide (melting point 2800℃) and high melting point carbon material which is difficult to be penetrated by slag as raw materials, adding various non-oxide additives and combining with carbon binder. As a kind of composite refractory material, magnesia carbon brick effectively utilizes the strong slag resistance of magnesia and the high thermal conductivity and low expansion of carbon to compensate for the poor spalling resistance of magnesia.

Magnesia Brick Manufacturing — Sintered, Fused & Unburned Types

Magnesia bricks are basic refractory products whose performance depends on more than MgO content alone. The manufacturing route and bond system influence the brick’s structure, thermal response, resistance to slag penetration, oxidation sensitivity and handling requirements. The main routes considered in industrial procurement are sintered magnesia brick, fused magnesia brick and unburned or chemical-bonded magnesia brick. This guide explains how these routes differ and what information a buyer should confirm before ordering. It does not replace the MZ-91, MZ-95 and MZ-97 technical data page. For grade-specific MgO, density, porosity, CCS and RUL values, see the MZ grade and performance guide.

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